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Vitamin A, vitamin C , a nutrient known for its importance in the manufacture of collagen, is being touted by some experts as a key player in keeping the complexion smooth. A daily dose of vitamin C of 300 to 500 milligrams is recommended to repair and maintain aging skin.Vitamin E, another free radical-fighting antioxidant, can also prevent skin damage from sun exposure when used topically, say researchers. But is recommend it for post-sun use rather than pre-sun use.